Organic Phosphates. III. Studies on Alcoholysis of Several Cyclic Phosphates.
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چکیده
منابع مشابه
Synthesis of inositol glycan cyclic phosphates.
An efficient synthesis of tri-, tetra-, and pentasaccharide cyclic phosphates 1-5, structurally related to natural inositol phosphate glycans, is reported. The title compounds were assembled by PhSeOTf-promoted glycosylation of the known glucosamine precursor, t-butyldimethylsilyl 2-azido-3,6-di-O-benzyl-2-deoxy-beta-D-glucopyranoside (8) with protected 1-methylthio mono-, di-, and trimannoside...
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The rate of methemoglobin reduction by ascorbic acid was accelerated in the presence of ATP,2,3-diphosphoglycerate (2,3-DPG), and inositol hexaphosphate (IHP). The acceleration was as much as three times, four times, and ten times in the presence of ATP, 2.3-DPG, and IHP at pH 7.0, respectively. The changes of the concentrations of methemoglobin and ascorbic acid during the methemoglobin reduct...
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Rubinstein J (1995) Cohtmn Flotation: Processes, Designs and Practices. New York: Gordon and Breach. Schubert Hand Bischofberger C (1979) On the optimization of hydrodynamics in flotation processes. In: Laskowski J (ed.) Proceedings of the 13th International Mineral Process Congress, pp. 1261-1287. Warsaw: Elsevier. Wills BA (1992) Introduction to Mineral Processing Technology, 5th edn, pp. 558...
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The recognition in the early 1960s by Morifusa Eto that tri-o-cresyl phosphate (TOCP) is hydroxylated by the cytochrome P450 system to an intermediate that spontaneously cyclizes to a neurotoxic phosphate (saligenin phosphate ester) ignited the interest in this group of compounds. Only the ortho isomer can cyclize and clinically cause Organo Phosphate Induced Delayed Neurotoxicity (OPIDN); the ...
متن کاملHemoglobin kinetics and the effect of organic phosphates.
A kinetic model based on allosteric mechanisms of cooperativity fits the experimentally observed phosphate dependence of hemoglobin reactions. Subunit inequivalence is found to be important in analyzing hemoglobin kinetics. The observed increase in the rate of deoxygenation in the presence of organic phosphates is primarily related to the increased rate of dissociation of the second oxygen mole...
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ژورنال
عنوان ژورنال: Pharmaceutical Bulletin
سال: 1957
ISSN: 0369-9471,1881-1345
DOI: 10.1248/cpb1953.5.208